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2018年10月05日
1H_NMR, 13CNMR スペクトル一覧 セスキテルペン
1H_NMR, 13CNMR スペクトル一覧 セスキテルペン
1H NMR: δ 0.87-0.92 (9H, 0.89 (s), 0.90 (d, J = 6.9 Hz), 0.91 (s)), 0.92-0.97 (6H, 0.95 (d, J = 6.9 Hz), 0.93 (s)), 1.22 (1H, dd, J = 10.0, 2.0 Hz), 1.20-1.76 (11H, 1.52 (dddd, J = 13.1, 3.3, 2.6, 2.0 Hz), 1.48 (qd, J = 6.9, 1.4 Hz), 1.50 (ddd, J = 13.4, 3.3, 2.5 Hz), 1.59 (ddddd, J = 13.1, 3.3, 3.0, 2.6, 2.5 Hz), 1.64 (ddd, J = 13.2, 3.0, 2.7 Hz), 1.39 (ddddd, J = 13.1, 10.3, 10.2, 3.3, 2.7 Hz), 1.38 (ddd, J = 13.4, 10.2, 3.3 Hz), 1.27 (ddd, J = 13.2, 10.3, 2.6 Hz), 1.45 (dddd, J = 13.0, 10.2, 4.8, 3.3 Hz), 1.71 (dddd, J = 13.0, 3.1, 2.6, 1.6 Hz), 1.40 (dddd, J = 13.1, 10.2, 10.0, 3.1 Hz)), 1.86 (1H, qddd, J = 6.9, 4.8, 1.6, 1.4 Hz).
δ (ppm)
16.1
18.6
19.8
19.8
28.1
28.3
28.3
32.0
32.1
32.2
34.7
38.3
38.8
41.9
48.8
1H NMR: δ 0.87-0.92 (9H, 0.89 (s), 0.90 (d, J = 6.9 Hz), 0.91 (s)), 0.92-0.97 (6H, 0.95 (d, J = 6.9 Hz), 0.93 (s)), 1.22 (1H, dd, J = 10.0, 2.0 Hz), 1.20-1.76 (11H, 1.52 (dddd, J = 13.1, 3.3, 2.6, 2.0 Hz), 1.48 (qd, J = 6.9, 1.4 Hz), 1.50 (ddd, J = 13.4, 3.3, 2.5 Hz), 1.59 (ddddd, J = 13.1, 3.3, 3.0, 2.6, 2.5 Hz), 1.64 (ddd, J = 13.2, 3.0, 2.7 Hz), 1.39 (ddddd, J = 13.1, 10.3, 10.2, 3.3, 2.7 Hz), 1.38 (ddd, J = 13.4, 10.2, 3.3 Hz), 1.27 (ddd, J = 13.2, 10.3, 2.6 Hz), 1.45 (dddd, J = 13.0, 10.2, 4.8, 3.3 Hz), 1.71 (dddd, J = 13.0, 3.1, 2.6, 1.6 Hz), 1.40 (dddd, J = 13.1, 10.2, 10.0, 3.1 Hz)), 1.86 (1H, qddd, J = 6.9, 4.8, 1.6, 1.4 Hz).
δ (ppm)
11.3
17.2
18.6
18.8
22.8
27.4
27.4
33.3
34.5
34.7
37.6
39.5
41.2
46.5
54.6
1H NMR: δ 0.87-0.94 (6H, 0.90 (d, J = 6.9 Hz), 0.91 (d, J = 6.9 Hz)), 0.96-0.97 (6H, 0.96 (s), 0.96 (s)), 1.22-1.72 (15H, 1.32 (dddd, J = 13.1, 9.8, 4.1, 1.4 Hz), 1.34 (dd, J = 18.2, 9.3 Hz), 1.33 (dd, J = 18.2, 6.4 Hz), 1.36 (dddd, J = 13.1, 10.3, 4.8, 3.2 Hz), 1.52 (ddddd, J = 12.9, 10.2, 4.1, 3.3, 1.9 Hz), 1.64 (dqt, J = 8.2, 6.9, 1.4 Hz), 1.52 (dddd, J = 9.3, 6.5, 6.4, 1.4 Hz), 1.59 (dddd, J = 10.2, 7.9, 4.8, 2.7 Hz), 1.59 (dddd, J = 10.2, 5.4, 5.0, 3.2 Hz), 1.55 (dddd, J = 13.1, 7.9, 5.0, 2.8 Hz), 1.57 (ddddd, J = 12.9, 9.8, 4.0, 3.3, 2.4 Hz), 1.66 (quintddd, J = 6.9, 5.4, 2.7, 1.9 Hz), 1.41 (dddd, J = 12.9, 3.3, 2.4, 1.9 Hz), 1.31 (dddd, J = 12.9, 10.2, 6.9, 3.3 Hz), 1.29 (dddd, J = 13.1, 8.2, 4.0, 1.9 Hz)), 1.72 (1H, ddd, J = 10.3, 6.5, 2.8 Hz).
δ (ppm)
18.6
19.5
24.3
25.9
25.9
28.3
32.5
34.6
35.8
36.2
36.7
37.0
37.4
40.9
48.4
1H NMR: δ 0.88-0.94 (6H, 0.91 (d, J = 7.0 Hz), 0.92 (d, J = 6.9 Hz)), 0.98-1.02 (6H, 1.00 (d, J = 6.8 Hz), 1.00 (d, J = 6.8 Hz)), 1.23-1.83 (15H, 1.64 (ddt, J = 12.9, 2.9, 2.7 Hz), 1.61 (dqd, J = 9.3, 6.9, 5.4 Hz), 1.50 (dtd, J = 12.0, 5.4, 1.4 Hz), 1.49 (septd, J = 6.8, 2.7 Hz), 1.52 (dddd, J = 13.3, 9.4, 7.6, 5.4 Hz), 1.60 (dddd, J = 13.3, 7.0, 5.3, 1.4 Hz), 1.45 (tqt, J = 10.3, 7.0, 2.8 Hz), 1.32 (dtd, J = 12.0, 9.3, 5.3 Hz), 1.51 (ddd, J = 13.1, 10.3, 2.9 Hz), 1.43 (ddd, J = 13.1, 10.3, 2.9 Hz), 1.75 (ddd, J = 13.1, 2.9, 2.7 Hz), 1.78 (ddd, J = 13.1, 2.9, 2.7 Hz), 1.32 (dtd, J = 13.1, 10.3, 2.9 Hz), 1.41 (dtd, J = 12.9, 10.3, 2.9 Hz), 1.54 (ddt, J = 13.1, 2.9, 2.7 Hz)), 1.78 (1H, ddd, J = 7.6, 7.0, 2.7 Hz).
δ (ppm)
16.6
21.6
22.7
22.7
25.2
28.6
30.6
31.2
31.2
31.6
35.4
35.4
43.8
48.3
55.8
guajan
1H NMR: δ 0.87-0.92 (9H, 0.89 (s), 0.90 (d, J = 6.9 Hz), 0.91 (s)), 0.92-0.97 (6H, 0.95 (d, J = 6.9 Hz), 0.93 (s)), 1.22 (1H, dd, J = 10.0, 2.0 Hz), 1.20-1.76 (11H, 1.52 (dddd, J = 13.1, 3.3, 2.6, 2.0 Hz), 1.48 (qd, J = 6.9, 1.4 Hz), 1.50 (ddd, J = 13.4, 3.3, 2.5 Hz), 1.59 (ddddd, J = 13.1, 3.3, 3.0, 2.6, 2.5 Hz), 1.64 (ddd, J = 13.2, 3.0, 2.7 Hz), 1.39 (ddddd, J = 13.1, 10.3, 10.2, 3.3, 2.7 Hz), 1.38 (ddd, J = 13.4, 10.2, 3.3 Hz), 1.27 (ddd, J = 13.2, 10.3, 2.6 Hz), 1.45 (dddd, J = 13.0, 10.2, 4.8, 3.3 Hz), 1.71 (dddd, J = 13.0, 3.1, 2.6, 1.6 Hz), 1.40 (dddd, J = 13.1, 10.2, 10.0, 3.1 Hz)), 1.86 (1H, qddd, J = 6.9, 4.8, 1.6, 1.4 Hz).
δ (ppm)
16.1
18.6
19.8
19.8
28.1
28.3
28.3
32.0
32.1
32.2
34.7
38.3
38.8
41.9
48.8
driman
1H NMR: δ 0.87-0.92 (9H, 0.89 (s), 0.90 (d, J = 6.9 Hz), 0.91 (s)), 0.92-0.97 (6H, 0.95 (d, J = 6.9 Hz), 0.93 (s)), 1.22 (1H, dd, J = 10.0, 2.0 Hz), 1.20-1.76 (11H, 1.52 (dddd, J = 13.1, 3.3, 2.6, 2.0 Hz), 1.48 (qd, J = 6.9, 1.4 Hz), 1.50 (ddd, J = 13.4, 3.3, 2.5 Hz), 1.59 (ddddd, J = 13.1, 3.3, 3.0, 2.6, 2.5 Hz), 1.64 (ddd, J = 13.2, 3.0, 2.7 Hz), 1.39 (ddddd, J = 13.1, 10.3, 10.2, 3.3, 2.7 Hz), 1.38 (ddd, J = 13.4, 10.2, 3.3 Hz), 1.27 (ddd, J = 13.2, 10.3, 2.6 Hz), 1.45 (dddd, J = 13.0, 10.2, 4.8, 3.3 Hz), 1.71 (dddd, J = 13.0, 3.1, 2.6, 1.6 Hz), 1.40 (dddd, J = 13.1, 10.2, 10.0, 3.1 Hz)), 1.86 (1H, qddd, J = 6.9, 4.8, 1.6, 1.4 Hz).
δ (ppm)
11.3
17.2
18.6
18.8
22.8
27.4
27.4
33.3
34.5
34.7
37.6
39.5
41.2
46.5
54.6
caryophyllan
1H NMR: δ 0.87-0.94 (6H, 0.90 (d, J = 6.9 Hz), 0.91 (d, J = 6.9 Hz)), 0.96-0.97 (6H, 0.96 (s), 0.96 (s)), 1.22-1.72 (15H, 1.32 (dddd, J = 13.1, 9.8, 4.1, 1.4 Hz), 1.34 (dd, J = 18.2, 9.3 Hz), 1.33 (dd, J = 18.2, 6.4 Hz), 1.36 (dddd, J = 13.1, 10.3, 4.8, 3.2 Hz), 1.52 (ddddd, J = 12.9, 10.2, 4.1, 3.3, 1.9 Hz), 1.64 (dqt, J = 8.2, 6.9, 1.4 Hz), 1.52 (dddd, J = 9.3, 6.5, 6.4, 1.4 Hz), 1.59 (dddd, J = 10.2, 7.9, 4.8, 2.7 Hz), 1.59 (dddd, J = 10.2, 5.4, 5.0, 3.2 Hz), 1.55 (dddd, J = 13.1, 7.9, 5.0, 2.8 Hz), 1.57 (ddddd, J = 12.9, 9.8, 4.0, 3.3, 2.4 Hz), 1.66 (quintddd, J = 6.9, 5.4, 2.7, 1.9 Hz), 1.41 (dddd, J = 12.9, 3.3, 2.4, 1.9 Hz), 1.31 (dddd, J = 12.9, 10.2, 6.9, 3.3 Hz), 1.29 (dddd, J = 13.1, 8.2, 4.0, 1.9 Hz)), 1.72 (1H, ddd, J = 10.3, 6.5, 2.8 Hz).
δ (ppm)
18.6
19.5
24.3
25.9
25.9
28.3
32.5
34.6
35.8
36.2
36.7
37.0
37.4
40.9
48.4
acoran
1H NMR: δ 0.88-0.94 (6H, 0.91 (d, J = 7.0 Hz), 0.92 (d, J = 6.9 Hz)), 0.98-1.02 (6H, 1.00 (d, J = 6.8 Hz), 1.00 (d, J = 6.8 Hz)), 1.23-1.83 (15H, 1.64 (ddt, J = 12.9, 2.9, 2.7 Hz), 1.61 (dqd, J = 9.3, 6.9, 5.4 Hz), 1.50 (dtd, J = 12.0, 5.4, 1.4 Hz), 1.49 (septd, J = 6.8, 2.7 Hz), 1.52 (dddd, J = 13.3, 9.4, 7.6, 5.4 Hz), 1.60 (dddd, J = 13.3, 7.0, 5.3, 1.4 Hz), 1.45 (tqt, J = 10.3, 7.0, 2.8 Hz), 1.32 (dtd, J = 12.0, 9.3, 5.3 Hz), 1.51 (ddd, J = 13.1, 10.3, 2.9 Hz), 1.43 (ddd, J = 13.1, 10.3, 2.9 Hz), 1.75 (ddd, J = 13.1, 2.9, 2.7 Hz), 1.78 (ddd, J = 13.1, 2.9, 2.7 Hz), 1.32 (dtd, J = 13.1, 10.3, 2.9 Hz), 1.41 (dtd, J = 12.9, 10.3, 2.9 Hz), 1.54 (ddt, J = 13.1, 2.9, 2.7 Hz)), 1.78 (1H, ddd, J = 7.6, 7.0, 2.7 Hz).
δ (ppm)
16.6
21.6
22.7
22.7
25.2
28.6
30.6
31.2
31.2
31.6
35.4
35.4
43.8
48.3
55.8
posted by easychemistry at 17:18
| NMRスペクトル集
